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Tin(IV) tetrahalide adducts with 4-amino-benzophenone

โœ Scribed by I.M. Vezzosi; A.F. Zanoli; G. Peyronel


Book ID
113374545
Publisher
Elsevier Science
Year
1980
Tongue
English
Weight
342 KB
Volume
36
Category
Article
ISSN
1386-1425

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A large number of SnX4\*2L and SnX4\*L-L tin-(IV) tctrahalide adducts were synthesized and analyzed (X = Cl, Br; L = MezO, EtzO, THF, Me& Et2S, THT, Me$e, MeCN, Me3CCN, Me&O, HMPA, TMPA; L-L = (MeOCH2-)2). Their cis or trans geometry was determined by infrared and Raman spectroscopy. For the SnC14 -

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The solid state configurations of 1: 1 and 1: 2 adducts formed by tin tetrahalides and titanium tetrachloride with /3-aminothione, CH,C(S)CH=C(NHCHa)CH3, (Me-S-NM+Me), tetradentate aminothione, H,[(sacac),en] and b-ketoamines R'C(O)CH=C(NHR)R', (R'4-NR-R2) have been investigated. The i.r. spectra of