Studies on adducts of tin tetrahalides and titanium tetrachloride with β-aminothiones and β-ketoamines

✍ Scribed by R.P. Singh; V.D. Gupta

• Book ID: 103905531
• Publisher: Elsevier Science
• Year: 1984
• Tongue: English
• Weight: 377 KB
• Volume: 40
• Category: Article
• ISSN: 1386-1425
• DOI: 10.1016/0584-8539(84)80071-9

✦ Synopsis

The solid state configurations of 1: 1 and 1: 2 adducts formed by tin tetrahalides and titanium tetrachloride with /3-aminothione, CH,C(S)CH=C(NHCHa)CH3, (Me-S-NM+Me), tetradentate aminothione, H,[(sacac),en] and b-ketoamines R'C(O)CH=C(NHR)R', (R'4-NR-R2) have been investigated. The i.r. spectra of the addition compounds suggested that the bi-and tetradentate aminothiones coordinated tin(W) and titanium(W) through the nitrogen atom and the b-ketoamines through the oxygen. The conducting behaviour of the products of tin tetrahalides in non-aqueous solvents of high dielectric constant exhibits some interesting trends with the change of the halide group.