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Adducts of tin(IV) tetrahalides with neutral lewis bases. III. Dynamic study by NMR

โœ Scribed by S.J. Ruzicka; C.M.P. Favez; A.E. Merbach


Publisher
Elsevier Science
Year
1977
Tongue
English
Weight
672 KB
Volume
23
Category
Article
ISSN
0020-1693

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Adducts of tin(IV) tetrahalides with neu
โœ S.J. Ruzicka; A.E. Merbach ๐Ÿ“‚ Article ๐Ÿ“… 1976 ๐Ÿ› Elsevier Science ๐ŸŒ English โš– 783 KB

A large number of SnX4\*2L and SnX4\*L-L tin-(IV) tctrahalide adducts were synthesized and analyzed (X = Cl, Br; L = MezO, EtzO, THF, Me& Et2S, THT, Me$e, MeCN, Me3CCN, Me&O, HMPA, TMPA; L-L = (MeOCH2-)2). Their cis or trans geometry was determined by infrared and Raman spectroscopy. For the SnC14 -