✦ LIBER ✦

Tin(II) chloride-mediated synthesis of 2-substituted benzoxazoles

✍ Scribed by Chan Sik Cho; Dong Tak Kim; Jiao Qiang Zhang; Son-Lam Ho; Tae-Jeong Kim; Sang Chul Shim

Publisher: Journal of Heterocyclic Chemistry
Year: 2002
Tongue: English
Weight: 38 KB
Volume: 39
Category: Article
ISSN: 0022-152X
DOI: 10.1002/jhet.5570390229

No coin nor oath required. For personal study only.

✦ Synopsis

Abstract

2‐Aminophenols react with an array of carboxylic acids in dioxane at 180° in the presence of tin(II) chloride to afford the corresponding 2‐substituted benzoxazoles in good yields. The reaction is applicable to a wide range of alkyl, alkenyl, aryl carboxylic acids.

📜 SIMILAR VOLUMES

Tin(II) Chloride-Mediated Synthesis of 2

Tin(II) Chloride-Mediated Synthesis of 2-Substituted Benzoxazoles.

✍ Chan Sik Cho; Dong Tak Kim; Jiao Qiang Zhang; Son-Lam Ho; Tae-Jeong Kim; Sang Ch 📂 Article 📅 2010 🏛 John Wiley and Sons ⚖ 26 KB

Hypervalent Iodine(III) Mediated Synthes

Hypervalent Iodine(III) Mediated Synthesis of 2-Substituted Benzoxazoles.

✍ Om Prakash; Anita Batra; Vijay Sharma; Rajesh K. Saini; Rajender S. Verma 📂 Article 📅 2005 🏛 John Wiley and Sons ⚖ 20 KB

Facile synthesis of 2-substituted benzox

Facile synthesis of 2-substituted benzoxazoles via ketenes

✍ T.O. Olagbemiro; M.O. Agho; O.J. Abayeh; J.O. Amupitan 📂 Article 📅 2010 🏛 Elsevier Science 🌐 English ⚖ 187 KB

Synthesis of Some 2-Aminonitroethanes vi

Synthesis of Some 2-Aminonitroethanes via Tin(II)chloride Mediated Addition Reaction of Bromonitromethane to Imines.

✍ Ali S. Mahasneh; Hazem Qaraqe 📂 Article 📅 2005 🏛 John Wiley and Sons ⚖ 13 KB 👁 1 views

Zirconium(IV) Oxide Chloride and Anhydro

Zirconium(IV) Oxide Chloride and Anhydrous Copper(II) Sulfate Mediated Synthesis of 2-Substituted Benzothiazoles.

✍ Firouz Matloubi Moghaddam; Hossein Ismaili; Ghasem Rezanejade Bardajee 📂 Article 📅 2006 🏛 John Wiley and Sons ⚖ 24 KB

Zirconium(IV) oxide chloride and anhydro

Zirconium(IV) oxide chloride and anhydrous copper(II) sulfate mediated synthesis of 2-substituted benzothiazoles

✍ Firouz Matloubi Moghaddam; Hossein Ismaili; Ghasem Rezanejade Bardajee 📂 Article 📅 2006 🏛 John Wiley and Sons 🌐 English ⚖ 409 KB

A simple, fast and efficient benign procedure has been developed for one-pot synthesis of 2-substituted benzothiazoles in the presence of zirconium(IV) oxide chloride octahydrate (ZrOCl 2 •8H 2 O) and anhydrous copper(II) sulfate. The reaction of 2-aminothiophenol with aldehydes and anhydrides was c