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Threshold energy dependence of intramolecular vibrational redistribution (IVR) rates of isolated polyatomic molecules

✍ Scribed by M.V. Kuzmin; A.A. Stuchebrukhov

Publisher: Elsevier Science
Year: 1985
Tongue: English
Weight: 403 KB
Volume: 119
Category: Article
ISSN: 0009-2614
DOI: 10.1016/0009-2614(85)85388-4

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✦ Synopsis

A thermodynamic Green's function technique is successfully applied to the calculation of IVR rates of polyatonfic molecul, The energy dependence of IVR rates has interesting threshold features: rates are zero below some critical energy Ec, aJ non-zero for higher energies. This dependence can be understood as a transition from regular to chaotic intramolecular motic

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