Three polyhalogenated tricyclo[5.1.0.03,5]octane compounds
β Scribed by Lynch, V. M. ;Baran Jnr, J. R. ;Lagow, R. J. ;Davis, B. E.
- Book ID
- 114511164
- Publisher
- International Union of Crystallography
- Year
- 1994
- Tongue
- English
- Weight
- 383 KB
- Volume
- 50
- Category
- Article
- ISSN
- 0108-2701
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It has been reported previously (1) that duroquinone, in contrast to many other p-quinones (2,3), reacts with diazomethane by direct addition at the carbonyl groups. We have reinvestigated this system and find that, in fact, the reaction proceeds bJ addition to the olefinic centres of the duroquinon
## Abstract The carbon and proton NMR spectra of __syn__β and __anti__βtricyclo[5.1.0.0^3,5^]octanes and their dichlorocarbene Cο£ΏH bond insertion products were determined by conventional 1D and 2D methods. Partially relaxed proton spectroscopy was carried out in some instances to aid in the separat