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Reaction of duroquinone with diazomethane: Formation of tricyclo[5,1,0,03,5]octane derivatives

✍ Scribed by W.C. Howell; M. Ktenas; J.M. MacDonald

Book ID: 104240764
Publisher: Elsevier Science
Year: 1964
Tongue: French
Weight: 246 KB
Volume: 5
Category: Article
ISSN: 0040-4039
DOI: 10.1016/s0040-4039(01)89497-1

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✦ Synopsis

It has been reported previously (1) that duroquinone, in contrast to many other p-quinones (2,3), reacts with diazomethane by direct addition at the carbonyl groups. We have reinvestigated this system and find that, in fact, the reaction proceeds bJ addition to the olefinic centres of the duroquinone. New structural formulas are assigned to each of the compounds arising from the reaction and a convenient method is elaborated for the synthesis of potentially interesting derivatives of the little-known

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