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Investigation of the conformations of compounds of the trans-tricyclo[5,1,0,03.5]octane series

✍ Scribed by B. A. Arbuzov; A. P. Timosheva; S. G. Vul'fson; A. N. Vereshchagin


Book ID
112440513
Publisher
Springer
Year
1973
Tongue
English
Weight
316 KB
Volume
22
Category
Article
ISSN
1573-9171

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πŸ“œ SIMILAR VOLUMES


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The six-membered ring of an anti-tricycle (~5.1.0.0.315] octane is shown by X-ray crystallography to be almost planar. The precise conformation agrees remarkably well with that obtained for the molecule in solution using lanthanide shift reagents.

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## Abstract The carbon and proton NMR spectra of __syn__‐ and __anti__‐tricyclo[5.1.0.0^3,5^]octanes and their dichlorocarbene Cο£ΏH bond insertion products were determined by conventional 1D and 2D methods. Partially relaxed proton spectroscopy was carried out in some instances to aid in the separat