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Conformational analysis of the anti-tricyclo[5.1.0.0.3,5] octane ring system: comparison of solution and solid-state geometries

✍ Scribed by W. Cocker; P.D. Cunningham; N.W.A. Geraghty; T. Higgins; P.J. McArdle

Publisher: Elsevier Science
Year: 1984
Tongue: French
Weight: 177 KB
Volume: 25
Category: Article
ISSN: 0040-4039
DOI: 10.1016/s0040-4039(01)91307-3

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✦ Synopsis

The six-membered ring of an anti-tricycle (~5.1.0.0.315] octane is shown by X-ray crystallography to be almost planar. The precise conformation agrees remarkably well with that obtained for the molecule in solution using lanthanide shift reagents.

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