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Three-electron oxidations. 11. Chromium(V) oxidation of alcohols

โœ Scribed by Hasan, Fariza; Rocek, Jan

Book ID
126473474
Publisher
American Chemical Society
Year
1976
Tongue
English
Weight
520 KB
Volume
98
Category
Article
ISSN
0002-7863

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๐Ÿ“œ SIMILAR VOLUMES

Oxidation of alcohols to carbonyl compou
Oxidation of alcohols to carbonyl compounds with chromium(V) reagents
โœ T.K. Chakraborty; S. Chandrasekaran ๐Ÿ“‚ Article ๐Ÿ“… 1980 ๐Ÿ› Elsevier Science ๐ŸŒ French โš– 235 KB

Two pentavalent chromium complexes have been used effectively for the oxidation of alcohols to carbonyl compounds. Oxidation of primary and secondary alcohols to carbonyl compounds are usually carried out with chromium&I) reagents. l-6 Chromium(V) is postulated as

Dipyridine-chromium(VI) oxide oxidation
Dipyridine-chromium(VI) oxide oxidation of alcohols in dichloromethane
โœ J.C. Collins; W.W. Hess; F.J. Frank ๐Ÿ“‚ Article ๐Ÿ“… 1968 ๐Ÿ› Elsevier Science ๐ŸŒ French โš– 216 KB

The extensive use of acid-labile protecting groups in organic syntheses prompted rapid adoption of dipyridine-chromium(VI) oxide 1 in pyridine as the reagent2 of choice for numerous conversions of secondary alcohols to ketones. 3 Yields of ketones are usually satisfactory but oxidations of primary