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Oxidation of alcohols to carbonyl compounds with chromium(V) reagents

✍ Scribed by T.K. Chakraborty; S. Chandrasekaran

Book ID
104225521
Publisher
Elsevier Science
Year
1980
Tongue
French
Weight
235 KB
Volume
21
Category
Article
ISSN
0040-4039

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✦ Synopsis

Two pentavalent chromium complexes have been used effectively for the oxidation of alcohols to carbonyl compounds.

Oxidation of primary and secondary alcohols to carbonyl compounds are usually carried out with chromium&I) reagents. l-6 Chromium(V) is postulated as

πŸ“œ SIMILAR VOLUMES

Chromium trioxide-3, 5-dimethylpyrazole
Chromium trioxide-3, 5-dimethylpyrazole complex as a reagent for oxidation of alcohols to carbonyl compounds
✍ E.J. Corey; G.W.J. Fleet πŸ“‚ Article πŸ“… 1973 πŸ› Elsevier Science 🌐 French βš– 162 KB

A wide range of alcohols can be oxidized efficiently and conveniently by a complex of chromium trioxide and 3,5\_dimethylpyrazole. Addition of one equivalent of 3,5\_dimethylpyrazole to a suspension o chromium trioxide in methylene chloride at room temperature forms a dark red solution; almost all