✦ LIBER ✦

Dipyridine-chromium(VI) oxide oxidation of alcohols in dichloromethane

✍ Scribed by J.C. Collins; W.W. Hess; F.J. Frank

Book ID: 104222685
Publisher: Elsevier Science
Year: 1968
Tongue: French
Weight: 216 KB
Volume: 9
Category: Article
ISSN: 0040-4039
DOI: 10.1016/s0040-4039(00)89494-0

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✦ Synopsis

The extensive use of acid-labile protecting groups in organic syntheses prompted rapid adoption of dipyridine-chromium(VI) oxide 1 in pyridine as the reagent2 of choice for numerous conversions of secondary alcohols to ketones.

3 Yields of ketones are usually satisfactory but oxidations of primary alcohols to aldehydes are capricious 3 and isolation of products from the pyridine medium often presents technical difficulties.

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