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The chromium VI oxidative cleavage of bridgehead alcohols

✍ Scribed by John J. Cawley; Vincent T. Spaziano

Book ID
104238650
Publisher
Elsevier Science
Year
1973
Tongue
French
Weight
178 KB
Volume
14
Category
Article
ISSN
0040-4039

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✦ Synopsis

It has been previously demonstrated' that only the intermediate oxidation states of chromium may cause oxidative cleavage of certain secondary alcohols. Chromium VI may reasonably be expected to accomplish a like cleavage if the substrate alcohol is sufficiently reactive. Recently, Rogek, and Radkowsky* have reported the chromic acid oxidation of l-methyl cyclobutanol,

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