Communication - Transiton States in Chromium(VI) Oxidation of Alcohols
β Scribed by Kwart, H.; Nickle, J. H.
- Book ID
- 124053389
- Publisher
- American Chemical Society
- Year
- 1973
- Tongue
- English
- Weight
- 360 KB
- Volume
- 95
- Category
- Article
- ISSN
- 0002-7863
No coin nor oath required. For personal study only.
π SIMILAR VOLUMES
The extensive use of acid-labile protecting groups in organic syntheses prompted rapid adoption of dipyridine-chromium(VI) oxide 1 in pyridine as the reagent2 of choice for numerous conversions of secondary alcohols to ketones. 3 Yields of ketones are usually satisfactory but oxidations of primary
It has been previously demonstrated' that only the intermediate oxidation states of chromium may cause oxidative cleavage of certain secondary alcohols. Chromium VI may reasonably be expected to accomplish a like cleavage if the substrate alcohol is sufficiently reactive. Recently, Rogek, and Radkow