𝔖 Bobbio Scriptorium
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Three-Electron bonds. II. SS and SCL three-electron bonds

✍ Scribed by Timothy Clark

Book ID
102306379
Publisher
John Wiley and Sons
Year
1982
Tongue
English
Weight
379 KB
Volume
3
Category
Article
ISSN
0192-8651

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✦ Synopsis

Abstract

Ab initio molecular orbital calculations are reported for the H~2~SSHΒ· and H~2~SClΒ· radicals and for the H~2~SClH^+Β·^ radical cation. The two neutral species are found to be very weakly bound van der Waals' complexes, whereas the H~2~SClH^+Β·^ radical cation is bound by 11.9 kcal mol^βˆ’1^ at MP2/4‐31G. The importance of charge in Οƒ* radicals is discussed.

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