𝔖 Bobbio Scriptorium
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Electron Apportionment in Three-Electron Bond-Breaking Processes

✍ Scribed by Robert D. Guthrie; Przemyslaw Maslak

Book ID
101763043
Publisher
Wiley (John Wiley & Sons)
Year
2010
Weight
57 KB
Volume
91
Category
Article
ISSN
0037-9646

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✦ Synopsis

When a molecule containing one unpalred electron undergoes rupture of an unsymmetrical bond to generate two separate molecules, there are at least two distinguishable ways inwhich the electrons can be apportioned. If the original molecule is a radical anion, the normal alternatives are those of eq. 1 and eq. 2.

πŸ“œ SIMILAR VOLUMES

Three-Electron bonds. II. SS and SCL thr
Three-Electron bonds. II. SS and SCL three-electron bonds
✍ Timothy Clark πŸ“‚ Article πŸ“… 1982 πŸ› John Wiley and Sons 🌐 English βš– 379 KB

## Abstract __Ab initio__ molecular orbital calculations are reported for the H~2~SSHΒ· and H~2~SClΒ· radicals and for the H~2~SClH^+Β·^ radical cation. The two neutral species are found to be very weakly bound van der Waals' complexes, whereas the H~2~SClH^+Β·^ radical cation is bound by 11.9 kcal mol