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Third-order nonlinear optical properties of bis(tetrabutylammonium)bis(4,5-dithiolato-1,3-dithiole-2-thione)copper

✍ Scribed by X.B. Sun; X.Q. Wang; Q. Ren; G.H. Zhang; H.L. Yang; L. Feng

Book ID
113785615
Publisher
Elsevier Science
Year
2006
Tongue
English
Weight
170 KB
Volume
41
Category
Article
ISSN
0025-5408

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## Abstract Bis(tetrabutylammonium)bis(2‐thioxo‐1,3‐dithiole‐4,5‐dithiolato)mercurate(II) was prepared and characterized by elemental analyses, electronic absorption, infrared and X‐ray powder diffraction spectroscopy. The specific heat of the crystal was measured to be 1878.2 J.mol^–1^K^–1^ at 300

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## Abstract The preparation and single crystal growth of bis(tetrabutylammonium)bis(4,5‐dithiolato‐1,3‐dithiole‐2‐thione)copper, (I), are described. The energy gap Eg of (I) is about 2.38 eV. The nonlinear optical susceptibility Ο‡^(3)^ is about 1.3Γ—10^‐3^ esu at 1064 nm. The characterization of (I)