Preparation, characterization, thermal and third-order nonlinear optical properties of bis(tetraethylammonium)bis(2-thioxo-1,3-dithiole-4,5-dithiolato)cuprate(II)
✍ Scribed by X.Q. Wang; Q. Ren; F.J. Zhang; W.F. Guo; X.B. Sun; J. Sun; H.L. Yang; G.H. Zhang; X.Q. Hou; D. Xu
- Book ID
- 113786304
- Publisher
- Elsevier Science
- Year
- 2008
- Tongue
- English
- Weight
- 400 KB
- Volume
- 43
- Category
- Article
- ISSN
- 0025-5408
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## Abstract Bis(tetrabutylammonium)bis(2‐thioxo‐1,3‐dithiole‐4,5‐dithiolato)mercurate(II) was prepared and characterized by elemental analyses, electronic absorption, infrared and X‐ray powder diffraction spectroscopy. The specific heat of the crystal was measured to be 1878.2 J.mol^–1^K^–1^ at 300
A novel bis (dmit) complex of copper (II), [(C 3 H 7 ) 4 N] 2 [Cu(dmit) 2 ] (1), where dmit is 2-thioxo-1,3-dithiole-4,5-dithiolate, was prepared and structurally characterized by X-ray single crystal diffraction. The copper (II) atom is tetracoordinated by four dmit S atoms, forming a nearly square