Preparation, crystal structure, spectrographic characterization, thermal and third order nonlinear optical properties of benzyltriethylamine bis(2-thioxo-1,3-dithiole-4,5-dithiolato)nickel(III)
β Scribed by X.Q. Wang; Q. Ren; H.L. Fan; J.W. Chen; Z.H. Sun; T.B. Li; X.T. Liu; G.H. Zhang; D. Xu; W.L. Liu
- Book ID
- 108166088
- Publisher
- Elsevier Science
- Year
- 2010
- Tongue
- English
- Weight
- 982 KB
- Volume
- 312
- Category
- Article
- ISSN
- 0022-0248
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A novel organometallic third-order nonlinear optical crystal: ethyltriphenylphosphonium bis(2-thioxo-1,3-dithiole-4,5-dithiolato)aurate(III) (ETPPADT) has been prepared, and large optical-quality single crystals have been grown by the solvent evaporation method. Its structural, optical and physicoch
## Abstract Bis(tetrabutylammonium)bis(2βthioxoβ1,3βdithioleβ4,5βdithiolato)mercurate(II) was prepared and characterized by elemental analyses, electronic absorption, infrared and Xβray powder diffraction spectroscopy. The specific heat of the crystal was measured to be 1878.2 J.mol^β1^K^β1^ at 300