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Preparation, crystal structure, spectrographic characterization, thermal and third-order nonlinear optical properties of benzyltriethylammonium bis(2-thioxo-1,3-dithiole-4,5-dithiolato)aurate(III) for all-optical switching applications

✍ Scribed by X.Q. Wang; Q. Ren; J.W. Chen; W.T. Yu; H.L. Fang; T.B. Li; H.J. Cong; X.T. Liu; L.Y. Zhu; G.H. Zhang; D. Xu

Book ID
113914191
Publisher
Elsevier Science
Year
2011
Tongue
English
Weight
940 KB
Volume
13
Category
Article
ISSN
1293-2558

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A novel organometallic third-order nonlinear optical crystal: ethyltriphenylphosphonium bis(2-thioxo-1,3-dithiole-4,5-dithiolato)aurate(III) (ETPPADT) has been prepared, and large optical-quality single crystals have been grown by the solvent evaporation method. Its structural, optical and physicoch

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## Abstract Bis(tetrabutylammonium)bis(2‐thioxo‐1,3‐dithiole‐4,5‐dithiolato)mercurate(II) was prepared and characterized by elemental analyses, electronic absorption, infrared and X‐ray powder diffraction spectroscopy. The specific heat of the crystal was measured to be 1878.2 J.mol^–1^K^–1^ at 300