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Thin Films and Surface Patterning with BEDT-TTF Based Charge Transfer Salts

✍ Scribed by H.Hau Wang; Catherine Y. Han; Dong-Youn Noh; Kyong-Soon Shin; Gerold A. Willing; Urs Geiser

Book ID
117539691
Publisher
Elsevier Science
Year
2003
Tongue
English
Weight
402 KB
Volume
137
Category
Article
ISSN
0379-6779

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New Molecular Charge Transfer Salts of BEDT-TTF, Bis(ethylenedithio) Tetrathiafulvalene, with Thiocyanato-Complex Anions: (BEDT-TTF)4[Fe(NCS)6]·CH2Cl2 and (BEDT-TTF)2[Cr(NCS)4(bipym)]·0.15H2O
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Two new charge transfer salts of BEDT-TTF, bis (ethylenedithio) tetrathiafulvalene, with thiocyanato-metal complex anions have been synthesized and characterized as (BEDT-TTF) 4 [Fe(NCS) 6 ] ' CH 2 Cl 2 and (BEDT-TTF) 2 [Cr(NCS) 4 (bipym)] ' 0.15H 2 O, where bipym ‫؍‬ 2,2-bipyrimidine. The Fe salt,

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Three new charge transfer salts of tetrathiafulvalene (TTF)based donors with selenocyanate-metal complex anions have been synthesized. The salts have been characterized as BEDT-TTF 4 [Cr(NCSe) 6 ] . CH 2 Cl 2 , II, TTF 3 [Cr(NCSe) 4 phen] 2 , III and BEDT-TTF 2 [Cr(NCSe) 4 phen] Á CH 2 Cl 2 , IV, wh