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Spectroscopic investigations of the BEDT-TTF charge transfer salts with NO3− anions (β″- and δ-phase)

✍ Scribed by R. Świetlik; A. Łapiński; M. Połomska; N.D. Kushch; A.N. Chekhlov

Book ID
116897400
Publisher
Elsevier Science
Year
2005
Tongue
English
Weight
390 KB
Volume
149
Category
Article
ISSN
0379-6779

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Two new charge transfer salts of BEDT-TTF, bis (ethylenedithio) tetrathiafulvalene, with thiocyanato-metal complex anions have been synthesized and characterized as (BEDT-TTF) 4 [Fe(NCS) 6 ] ' CH 2 Cl 2 and (BEDT-TTF) 2 [Cr(NCS) 4 (bipym)] ' 0.15H 2 O, where bipym ‫؍‬ 2,2-bipyrimidine. The Fe salt,

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The structure of the Fe salt is triclinic (a = 9.391( ), b = 12.730(3), c = 19.148(3) A; α = 104.11(2)°, β = 92.60(2)°, γ = 98.64(2)°; space group PT 1, Z = 1). 2 The BEDT-TTF molecules are arranged in pentamerised stacks with the sequence … BACAB …