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Thermolysis, photolysis, and oxidation of an overcrowded 1,3,2-dithiastannetane derivative

✍ Scribed by Norihiro Tokitoh; Verena Stresing; Yasusuke Matsuhashi; Renji Okazaki

Publisher
John Wiley and Sons
Year
1995
Tongue
English
Weight
430 KB
Volume
6
Category
Article
ISSN
1042-7163

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✦ Synopsis

Abstract

Reactions of a sterically crowded 1,3,2‐dithiastannetane derivative bearing 2,4,6‐tris[bis(trimethylsilyl)methyl]phenyl (=Tbt) and 2,4,6‐triisopropylphenyl (=Tip) groups on the tin atom are described. Both thermolysis and photolysis of the 1,3,2‐dithiastannetane [Tbt(Tip)SnS~2~CPh~2~] resulted in the formation of products derived from the corresponding stannanethione [Tbt(Tip)Sn=S], while the oxidation reaction by m‐chloroperbenzoic acid gave a novel tincontaining heterocyclic system, an 1,2,4,5‐oxadithiastannolane derivative.

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