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Thermolysis and photolysis of 1,3,4-oxathiazole-2-ones: I

✍ Scribed by J.E. Franz; L.L. Black

Publisher
Elsevier Science
Year
1970
Tongue
French
Weight
189 KB
Volume
11
Category
Article
ISSN
0040-4039

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✦ Synopsis

The thermolysis and photolysis of various oxazoles, diazoles and triazoles 1 have'been reported (la,lb) to generate labile 1,3-dipoles (nitrenes) z which subsequently rearrange to cumulene structures 3 or react with certain dipolar-ophiles (when present) to yield 1,3-dipolar adducts 4.

Z=

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