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Thermolysis of 7-isopropylidene-2,3-diazabicyclo [2.2.1] hept-2-ene in the presence of spin trap

✍ Scribed by Jimmy S. Hwang; Mohammad Nahid Siddiqui; Ahmed M. Bukhari


Publisher
Elsevier Science
Year
1991
Tongue
French
Weight
266 KB
Volume
32
Category
Article
ISSN
0040-4039

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Thermal deasetation of difluoro-and tetrafluoro-2,3-diasabicyclo[3.2.0lhept-2-enes proceed via two parallel mechanistic pathways, one involving formation of a diradical via simple N2 loss, and the other proceeding via a retro-dipolar cycloadd~on process. A key finding was the absence of isolation of