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Preparative uv-laser photochemistry of the azoalkane spiro(2,3-diazabicyclo [2.2.1]hept-2-ene-7′,1-cyclopropane): Trapping of the 1,4-Diradical 2-(3-Cyclopentenyl) ethyl by Molecular Oxygen

✍ Scribed by Waldemar Adam; Klaus Hannemann; Peter Hössel


Publisher
Elsevier Science
Year
1984
Tongue
French
Weight
241 KB
Volume
25
Category
Article
ISSN
0040-4039

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Competitive diradical and diazoalkane fo
✍ Waldemar Adam; William D. Gillaspey 📂 Article 📅 1983 🏛 Elsevier Science 🌐 French ⚖ 243 KB

On laser photolysis of azoalkane 1 at elevated temperature, besides the expected denitrogenation into the tricyclane 2 via 1,3-diradical 2, the diazoalkane Z\_ is directly observed, denitrogenating into vinylcyclopentene 2. The bicyclo[2.2.llheptane-2,6-diyl diradical 2, in principle accessible via