On the mechanism of the benzophenone-sensitized photolysis of 2,3-diazabicyclo[2.2.1]hept-2-ene in the laser jet: Evidence for intermolecular triplet diradical reactions
β Scribed by Adam, Waldemar ;Finzel, Ralf ;Walther, Barbara
- Publisher
- Wiley (John Wiley & Sons)
- Year
- 1993
- Tongue
- English
- Weight
- 504 KB
- Volume
- 126
- Category
- Article
- ISSN
- 0009-2940
No coin nor oath required. For personal study only.
π SIMILAR VOLUMES
Picosecond and nanosecond dynamics of the ion pair produced by the electron transfer reaction between the triplet state benzophenone ('BP\*) and 1,4-diazabicyclo[ 2.2.2loctane (DABCO) wasinvestigated by means oftransientabsorption spectroscopy and laser-induced photoconductivity measurement. It has
Despite an extensive literature, controversy about the Diels-Alder reaction mechanism still exists. For the thermal dimerization of 1,3-butadiene, for example, a concerted one-step [I] or two-stage [2] mechanism, a mixture of orbital symmetry allowed and forbidden cycloadditions 131, as well as a tw