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Thermolysis of 1,3,8-Nonatriyne: Evidence for Intramolecular [2 + 4] Cycloaromatization to a Benzyne Intermediate

✍ Scribed by Bradley, Alexander Z.; Johnson, Richard P.


Book ID
118052291
Publisher
American Chemical Society
Year
1997
Tongue
English
Weight
87 KB
Volume
119
Category
Article
ISSN
0002-7863

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✍ Roll Huisgen; Joaquin Plumet Ortega πŸ“‚ Article πŸ“… 1978 πŸ› Elsevier Science 🌐 French βš– 193 KB

Tetracyanoethylene (TCNE) belongs to the most active dienophiles in . the Diels-Alder reaction.' Trans-fixed 1,3-dienes, however, combine with TCNE in 2+2 cycloadditions to give vinylcyclobutanes; 293 the second double bond effects an activation, No. 41 ACKNOWLEDGMENT. J.P.O. expresses his gratitude