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[2 + 1]- Versus [4 + 2]-cycloadditions of Fischer carbene complexes with 1,3-dienes. Evidence for a zwitterionic intermediate in a cyclopropanation reaction

✍ Scribed by Wulff, William D.; Yang, Dominic C.; Murray, Christopher K.


Book ID
126150032
Publisher
American Chemical Society
Year
1988
Tongue
English
Weight
428 KB
Volume
110
Category
Article
ISSN
0002-7863

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Evidence for a zwitterionic intermediate
✍ Roll Huisgen; Joaquin Plumet Ortega πŸ“‚ Article πŸ“… 1978 πŸ› Elsevier Science 🌐 French βš– 193 KB

Tetracyanoethylene (TCNE) belongs to the most active dienophiles in . the Diels-Alder reaction.' Trans-fixed 1,3-dienes, however, combine with TCNE in 2+2 cycloadditions to give vinylcyclobutanes; 293 the second double bond effects an activation, No. 41 ACKNOWLEDGMENT. J.P.O. expresses his gratitude

ChemInform Abstract: Formal [4 + 3], [4
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## Abstract ChemInform is a weekly Abstracting Service, delivering concise information at a glance that was extracted from about 100 leading journals. To access a ChemInform Abstract of an article which was published elsewhere, please select a β€œFull Text” option. The original article is trackable v