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Unusual [3+1] Cycloaddition of a Stable Silylene with a 2,3-Diazabuta-1,3-diene versus [4+1] Cycloaddition toward a Buta-1,3-diene

โœ Scribed by Xiong, Yun; Yao, Shenglai; Driess, Matthias


Book ID
120483394
Publisher
American Chemical Society
Year
2010
Tongue
English
Weight
816 KB
Volume
29
Category
Article
ISSN
0276-7333

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Cycloaddition reactions of 2,4-diphenyl-
โœ Giorgio Abbiati; Alessandro Cirrincione de Carvalho; Elisabetta Rossi ๐Ÿ“‚ Article ๐Ÿ“… 2003 ๐Ÿ› Elsevier Science ๐ŸŒ French โš– 142 KB

The cycloaddition reactions of 1-p-tolyl and 1-benzyl-2,4-diphenyl-1,3-diazabuta-1,3-dienes with a variety of aryl and alkyl isocyanate and isothiocyanate are described. The reaction mechanism is also discussed.