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Evidence for a 1,4-dioxy diradical as an intermediate in the thermal decomposition of 3,3-dibenzyl-1,2-dioxetane

✍ Scribed by Adam, Waldemar; Heil, Markus


Book ID
127129272
Publisher
American Chemical Society
Year
1992
Tongue
English
Weight
394 KB
Volume
114
Category
Article
ISSN
0002-7863

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Evidence for a diradical intermediate in
✍ G. Huybrechts; B. Van Mele πŸ“‚ Article πŸ“… 1978 πŸ› John Wiley and Sons 🌐 English βš– 254 KB

Despite an extensive literature, controversy about the Diels-Alder reaction mechanism still exists. For the thermal dimerization of 1,3-butadiene, for example, a concerted one-step [I] or two-stage [2] mechanism, a mixture of orbital symmetry allowed and forbidden cycloadditions 131, as well as a tw