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Thermolyse von Tetramethyl-1,2-dioxetan

✍ Scribed by Dr. Peter Lechtken; Dr. Günther Höhne

Publisher
John Wiley and Sons
Year
1973
Tongue
English
Weight
208 KB
Volume
85
Category
Article
ISSN
0044-8249

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## Abstract Unter Lichteinwirkung zerfällt Tetramethyl‐1,2‐dioxetan (**1**) in zwei Moleküle Aceton mit einer Quantenausbeute Φ ≥ **1**. Licht der Wellenlänge λ ≤ 300 nm führt in einer adiabatischen Photoreaktion mit hoher (quantitativer) Ausbeute zu Aceton im elektronisch angeregten Zustand, beste

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The thermal decomposition of tetramethyl-1,2-dioxetsnc (RID) sorbed into zeolite Y containing Eu3+ ions and 2,2'-bipyridine (samples abbreviated as ZYEBT) has been investigated. Decompoeition of RID yields, by ener y tranefer processes, the Eu3' ion.

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## Abstract A computerized method is given for the evaluation of Arrhenius parameters which describe the chemiluminescent decomposition of tetramethyl‐1,2‐dioxetane. The parameters were determined in several solvents by linear regression methods and the equation ln ln \documentclass{article}\pagest