The reversible decomposition voltage of sodium nitrate was measured after electrolysis current was switched off in a cell containing the molten salt and platinum electrodes. The residual reversible cell is represented by the following scheme: Na(l)/NaNO,(l)/NO,,O,,Pt. (I) The theoretical standard e
Thermodynamics of iron/molten-sodium-nitrate
✍ Scribed by S.L. Marchiano; A.J. Arvía
- Publisher
- Elsevier Science
- Year
- 1972
- Tongue
- English
- Weight
- 525 KB
- Volume
- 17
- Category
- Article
- ISSN
- 0013-4686
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✦ Synopsis
Potential/pO*-diagrams have been developed for the iron/molten-sodium-nitrate system at 600 and 700°K. Four well-defined regions corresponding respectively to metal corrosion, immunity, passivity and passivity breakdown are shown in the diagrams. R&urn&On a d&eloppB les diagrammes potentiel/pOa-pour le systeme fer/nitrate de sodium fondu ZL des temperatures de 600 et 700°K. Ces diagrammes montrent quatre regions bien d&m& qui correspondent a la corrosion du metal, Zt I'immunite, a la passivite et & la rupture de la pellicule passive respectivement.
📜 SIMILAR VOLUMES
## Abutraet-Potentiom titrations of dilute solutions of silver nitrate in molten KNO,-Ba(NO,), with potassium halides have b+n carried out. The solubility products of AgCl, A d solvent at 350" were found to be. ( 7.91 f O-35) x 1O-s, (4023 f O-23) x lo+ an Br and AgI in this (l-964 f O-39) x IO-(m
Abstmct-The molten binary mixture Z&l,-N&l was studied by means of emf measurements on galvanic cells. In these cells Pyrex glass functions as a sodium indicator electrode. The erupt fret enthalpy of mixing at 600°C has been calculated from the emf measuremen ts. The ZnClrNaCl mixture shows a strong