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Voltammetry of iron in molten lithium fluoride-potassium fluoride-sodium fluoride

✍ Scribed by D.L. Manning

Publisher
Elsevier
Year
1963
Weight
541 KB
Volume
6
Category
Article
ISSN
0368-1874

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Transport numbers in molten fluoridesβ€”I.
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The external transport number of Naf in molten NaF was determined to be 064 & 0.05 by a tracer technique. A boron-nitride crucible was used as reference; it also served as a diaphragm separating the anolyte and the catholyte. Viscous flow could not be avoided completely, but was corrected for by per

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Splitting of the monomer bands was also observed; it is attributed to cis-trans-isomerism; the band of shorter wavelength is assigned to the all-trans-form, that of longer wavelength to a mono-cis-isomer that arises by rotation around the C-2/C-8 bond