Thermodynamic conditions for the formation of dioxin
✍ Scribed by Dr.-Ing. Philip John Spencer; Prof. Dr.-Ing. Dieter Neuschütz
- Publisher
- John Wiley and Sons
- Year
- 1992
- Tongue
- English
- Weight
- 335 KB
- Volume
- 15
- Category
- Article
- ISSN
- 0930-7516
No coin nor oath required. For personal study only.
📜 SIMILAR VOLUMES
In this note we are concerned with the linear theory of the thermodynamics of dielectric materials in the presence of memory e!ects for heat #ux. Restrictions imposed on the assumed constitutive equations by Thermodynamics are "rst determined. Then, we introduce a particular maximal free energy, tha
The standard molar enthalpy of combustion of dibenzo-p-dioxin (DD) was measured at T = 298.15 K by static-bomb combustion calorimetry: c H o m (cr) = -(5723.8 ± 1.4) kJ • mol -1 . The standard molar enthalpy of sublimation of this compound was measured by microcalorimetry: g cr H o m = (91.45 ± 0.76
The standard molar energy of combustion of crystalline 2-chlorodibenzo-p-dioxin was determined by rotating-bomb calorimetry: DcU°m = -(5573.622.8) kJ•mol -1 . The standard molar enthalpy of sublimation was measured in a Calvet microcalorimeter: DsubH°m = (97.2420.55) kJ•mol -1 . Using these results,
Literature values of ⌬G°(change in Gibbs free energy), ⌬H°(change in enthalpy), and T⌬S°(temperature times change in entropy) for 1:1 complex formation by ␣-, -, and ␥-cyclodextrins constitute normally distributed populations with the following statistical parameters (all energy quantities in kcal