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Thermochemistry of Solution of Fe(III) and Mn(III) Complexes with Natural Porphyrins

✍ Scribed by M. B. Berezin


Book ID
110312442
Publisher
Springer
Year
2001
Tongue
English
Weight
48 KB
Volume
71
Category
Article
ISSN
1070-3632

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Apoconalbumin binds \_Mn(II) at two sites with association constants of K1 = 7(%1) x lo4 and Kz = 0.4(?0.25) x lo4 M-l. The binding is tighter in the presence of excess bicarbonate resulting in K1 = l-8(\*0.2) X lo5 and K2 = 3(+2) X IO4 M-l. The electron paramagnetic resonance spectrum (at both 9 an