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Electrochemical reduction of Fe(III), Cr(III), and Mn(III) porphyrin complexes in DMSO

✍ Scribed by S. A. Klyuev; V. B. Sheinin; B. D. Berezin; D. V. Tsyganov; S. V. Vodzinskii


Book ID
112448800
Publisher
Springer
Year
1991
Tongue
English
Weight
187 KB
Volume
40
Category
Article
ISSN
1573-9171

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Apoconalbumin binds \_Mn(II) at two sites with association constants of K1 = 7(%1) x lo4 and Kz = 0.4(?0.25) x lo4 M-l. The binding is tighter in the presence of excess bicarbonate resulting in K1 = l-8(\*0.2) X lo5 and K2 = 3(+2) X IO4 M-l. The electron paramagnetic resonance spectrum (at both 9 an