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Unsymmetrical Bimetallic Complexes with M II –(μ-OH)–M III Cores (M II M III = Fe II Fe III , Mn II Fe III , Mn II Mn III ): Structural, Magnetic, and Redox Properties

✍ Scribed by Sano, Yohei; Weitz, Andrew C.; Ziller, Joseph W.; Hendrich, Michael P.; Borovik, A. S.


Book ID
121187904
Publisher
American Chemical Society
Year
2013
Tongue
English
Weight
450 KB
Volume
52
Category
Article
ISSN
0020-1669

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Apoconalbumin binds \_Mn(II) at two sites with association constants of K1 = 7(%1) x lo4 and Kz = 0.4(?0.25) x lo4 M-l. The binding is tighter in the presence of excess bicarbonate resulting in K1 = l-8(\*0.2) X lo5 and K2 = 3(+2) X IO4 M-l. The electron paramagnetic resonance spectrum (at both 9 an