Thermochemistry of gaseous manganese oxides and hydroxides
β Scribed by Hildenbrand, D. L.; Lau, K. H.
- Book ID
- 121080431
- Publisher
- American Institute of Physics
- Year
- 1994
- Tongue
- English
- Weight
- 691 KB
- Volume
- 100
- Category
- Article
- ISSN
- 0021-9606
- DOI
- 10.1063/1.466783
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π SIMILAR VOLUMES
A comparison of the behaviour of commercial electrochemical manganese dioxide (y\_MnO,) and non-stoichiometric anodic Mn,O,(OH), was made. Anodic oxide proves to he composed mainly by MnO, (ramsdellite) and MnOOH (manganite), and contains more water and OH-than y-MnO,. Hydroxide ions were shown to d
The N(2), H(2)O, and NH(3) adsorption properties on hollandite-type (H-Hol) and birnessite-type (H-Bir) hydrous manganese oxides were compared with those on zeolitic crystals. It was found that the effective pore openings of H-Bir and H-Hol are below 0.3 nm. Although the geometric spaces on H-Bir an