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Comparison of Gaseous Molecular Adsorption Properties of Microporous Manganese Oxides and Crystalline Aluminosilicates

✍ Scribed by Z.-M. Wang; H. Kanoh

Book ID
102580710
Publisher
Elsevier Science
Year
2001
Tongue
English
Weight
62 KB
Volume
236
Category
Article
ISSN
0021-9797

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✦ Synopsis

The N(2), H(2)O, and NH(3) adsorption properties on hollandite-type (H-Hol) and birnessite-type (H-Bir) hydrous manganese oxides were compared with those on zeolitic crystals. It was found that the effective pore openings of H-Bir and H-Hol are below 0.3 nm. Although the geometric spaces on H-Bir and H-Hol available for physical adsorption from a gaseous phase are much smaller than those on zeolites, they can provide a strong chemisorption field for H(2)O and NH(3) intercalation. Copyright 2001 Academic Press.

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