The parameters of the electrocapillary maximum of mercury, ymsx and Emax, were determined in aqueous sodium azide solutions of concentration ranging between 0.05 and 2.0 M at 25Β°C. Two sets of measurements were performed. Tn one set, the nce was used as a reference electrode of constant composition,
Thermochemistry of azides I. The standard enthalpy of formation of ammonium azide and of the azide ion
β Scribed by Arthur Finch; P.J Gardner; A.J Head; Wu Xiaoping
- Publisher
- Elsevier Science
- Year
- 1990
- Tongue
- English
- Weight
- 305 KB
- Volume
- 22
- Category
- Article
- ISSN
- 0021-9614
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The differential capacitance of mercury in O.l, O-5,0\*7, 1.0,1\*3 and 2.0 M aqueous sodium azide solutions was measured at 25Β°C as a function of polarization with respect to the Ag/AgN, electrode in the same solution. Following current theories, the differential capacitance curve is compared morpho
The calculations reported here atign a charge qN = -0.52 eIectron units to the terminal nitrogen atoms in the azide ion and a value of 141.9 M mole4 to the enthaipy of formation of thejaseous azide ion, A@fl&)).fhe, total Iattia? potential energies\_? found to be: EpotfNaN3) = 725.1 kJ mole and E&Rb