Thermochemistry of 1,2-dioxetane and its methylated derivatives. Estimate of activation parameters
✍ Scribed by O'Neal, H. Edward.; Richardson, William Harry.
- Book ID
- 127249884
- Publisher
- American Chemical Society
- Year
- 1970
- Tongue
- English
- Weight
- 603 KB
- Volume
- 92
- Category
- Article
- ISSN
- 0002-7863
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## Abstract 3‐Methyl‐3‐(3‐pentyl)‐1,2‐dioxetane **1** and 3‐methyl‐3‐(2,2‐dimethyl‐1‐propyl)‐1,2‐dioxetane **2** were synthesized in low yield by the α‐bromohydroperoxide method. The activation parameters were determined by the chemiluminescence method (for **1** ΔH‡ = 25.0 ± 0.3 kcal/mol, ΔS‡ = −1
## Abstract 3‐Methyl‐3‐(3‐pentyl)‐1,2‐dioxetane **1** and 3‐methyl‐3‐(2,2‐dimethyl‐1‐propyl)‐1,2‐dioxetane **2** were synthesized in low yield by the α‐bromohydroperoxide method. The activation parameters were determined by the chemiluminescence method (for **1** ΔH‡ = 25.0 ± 0.3 kcal/mol, ΔS‡ = −1