Thermolysis of dioxetanes: activation parameters for cis- and trans-3,4-dialkyl-1,2-dioxetanes
✍ Scribed by Baumstark, Alfons L.; Dunams, Tambra; Roskamp, Peter C.; Wilson, Catherine E.
- Book ID
- 126046838
- Publisher
- American Chemical Society
- Year
- 1983
- Tongue
- English
- Weight
- 446 KB
- Volume
- 48
- Category
- Article
- ISSN
- 0022-3263
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## Abstract trans‐3‐Methyl‐4‐(__p__‐anisyl)‐1,2‐dioxetane 1, trans‐3‐methyl‐4‐(__o__‐anisyl)‐1,2‐dioxetane __2__, 3‐methyl‐3‐benzyl‐1,2‐dioxetane __3__, and 3‐methyl‐3‐p‐methoxybenzyl‐1,2‐dioxetane __4__ were synthesized in low yield by the β‐bromo hydroperoxide method. The activation parameters we
## Abstract 3‐Methyl‐3‐(3‐pentyl)‐1,2‐dioxetane **1** and 3‐methyl‐3‐(2,2‐dimethyl‐1‐propyl)‐1,2‐dioxetane **2** were synthesized in low yield by the α‐bromohydroperoxide method. The activation parameters were determined by the chemiluminescence method (for **1** ΔH‡ = 25.0 ± 0.3 kcal/mol, ΔS‡ = −1
## Abstract 3‐Methyl‐3‐(3‐pentyl)‐1,2‐dioxetane **1** and 3‐methyl‐3‐(2,2‐dimethyl‐1‐propyl)‐1,2‐dioxetane **2** were synthesized in low yield by the α‐bromohydroperoxide method. The activation parameters were determined by the chemiluminescence method (for **1** ΔH‡ = 25.0 ± 0.3 kcal/mol, ΔS‡ = −1