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Thermolysis of dioxetanes: 3,3-diethyl-1,2-dioxetane and 3,3-dimethyl-4-ethyl-1,2-dioxetane

โœ Scribed by Baumstark, Alfons L.; Dunams, Tambra


Book ID
127104327
Publisher
American Chemical Society
Year
1982
Tongue
English
Weight
406 KB
Volume
47
Category
Article
ISSN
0022-3263

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๐Ÿ“œ SIMILAR VOLUMES


The unexpected thermal instability of 3,
โœ A.L. Baumstark; C.E. Wilson ๐Ÿ“‚ Article ๐Ÿ“… 1979 ๐Ÿ› Elsevier Science ๐ŸŒ French โš– 161 KB

3,4\_Tetramethylene-and cis-3,4-diethyl-1,2-dioxetane (l\_ and 2!) were prepared and characterized (for i-Ea =22.5 kcal/mole,log A=12.8; for 2 -Ea =24.5 kcal/mole, log A=13.1). 1,2-Dioxetanes undergo thermal decomposition to produce two carbonyl fragments, one of which can be generated in an excited