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Additions and Corrections - The Thermochemistry of 1,2-Dioxetane and Its Methylated Derivatives. An Estimate of Activation Parameters.

✍ Scribed by O'Neal, H.; Richardson, William


Book ID
125952211
Publisher
American Chemical Society
Year
1971
Tongue
English
Weight
115 KB
Volume
93
Category
Article
ISSN
0002-7863

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📜 SIMILAR VOLUMES


Thermolysis of 3-alkyl-3-methyl-1,2-diox
✍ Alfons L. Baumstark; Sean L. Anderson; Chariety J. Sapp; Pedro C. Vasquez 📂 Article 📅 2001 🏛 John Wiley and Sons 🌐 English ⚖ 72 KB

## Abstract 3‐Methyl‐3‐(3‐pentyl)‐1,2‐dioxetane **1** and 3‐methyl‐3‐(2,2‐dimethyl‐1‐propyl)‐1,2‐dioxetane **2** were synthesized in low yield by the α‐bromohydroperoxide method. The activation parameters were determined by the chemiluminescence method (for **1** ΔH‡ = 25.0 ± 0.3 kcal/mol, ΔS‡ = −1

Thermolysis of 3-alkyl-3-methyl-1,2-diox
✍ Alfons L. Baumstark; Sean L. Anderson; Chariety J. Sapp; Pedro C. Vasquez 📂 Article 📅 2001 🏛 John Wiley and Sons 🌐 English ⚖ 124 KB

## Abstract 3‐Methyl‐3‐(3‐pentyl)‐1,2‐dioxetane **1** and 3‐methyl‐3‐(2,2‐dimethyl‐1‐propyl)‐1,2‐dioxetane **2** were synthesized in low yield by the α‐bromohydroperoxide method. The activation parameters were determined by the chemiluminescence method (for **1** ΔH‡ = 25.0 ± 0.3 kcal/mol, ΔS‡ = −1