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Thermochemistry and Kinetics of the Reaction of 1-Methylallyl Radicals with Molecular Oxygen

โœ Scribed by Knyazev, Vadim D.; Slagle, Irene R.

Book ID
126329461
Publisher
American Chemical Society
Year
1998
Tongue
English
Weight
123 KB
Volume
102
Category
Article
ISSN
1089-5639

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The kinetics and mechanism of the gaseous reaction of vinyl radicals with molecular oxygen have been studied at 296 K. The products formed are HCO and H2C0. The rate constant is 1.0 X 10-r' cm3 molecule-' s-\* and is independent of pressure between 0.4 and 4 Torr.