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Kinetics and Thermochemistry of the Reaction of 2-Chloroallyl Radicals with Molecular Oxygen

โœ Scribed by Shestov, Alexander A.; Knyazev, Vadim D.

Book ID
127007920
Publisher
American Chemical Society
Year
2004
Tongue
English
Weight
74 KB
Volume
108
Category
Article
ISSN
1089-5639

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โœ Jong-Yoon Park; Michael C. Heaven; David Gutman ๐Ÿ“‚ Article ๐Ÿ“… 1984 ๐Ÿ› Elsevier Science ๐ŸŒ English โš– 501 KB

The kinetics and mechanism of the gaseous reaction of vinyl radicals with molecular oxygen have been studied at 296 K. The products formed are HCO and H2C0. The rate constant is 1.0 X 10-r' cm3 molecule-' s-\* and is independent of pressure between 0.4 and 4 Torr.