The reaction of CF, with NO, was studied at 296 2 2 K using two different absolute techniques Absolute rate constants of ( I 6 ? 0.3) X lo-" and ( 2 1-03+07) X lo-" cm3 molecule-' s-' were derived by IR fluorescence and UV absorption spectroscopy, respectively The reaction proceeds via two reaction
Kinetics and mechanism of the reaction of vinyl radicals with molecular oxygen
β Scribed by Jong-Yoon Park; Michael C. Heaven; David Gutman
- Publisher
- Elsevier Science
- Year
- 1984
- Tongue
- English
- Weight
- 501 KB
- Volume
- 104
- Category
- Article
- ISSN
- 0009-2614
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β¦ Synopsis
The kinetics and mechanism of the gaseous reaction of vinyl radicals with molecular oxygen have been studied at 296 K.
The products formed are HCO and H2C0. The rate constant is 1.0 X 10-r' cm3 molecule-' s-* and is independent of pressure between 0.4 and 4 Torr.
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