The protonation energetics of lactic acid (LA) were experimentally determined by the kinetic method including the entropy effect. The values (proton affinity, PA(LA) = 817.4 +/- 4.3 kJ mol(-1); protonation entropy, DeltaS degrees (p)(LA) = -2 +/- 5 J K(-1) mol(-1); gas-phase basicity, GB(LA) = 784.5
✦ LIBER ✦
Thermochemical and structural properties of DMAN-“proton sponges”
✍ Scribed by Juan Z. Dávalos; Alexsandre F. Lago; José C.S. Costa; Luís M.N.B.F. Santos; Javier González
- Book ID
- 116630464
- Publisher
- Elsevier Science
- Year
- 2012
- Tongue
- English
- Weight
- 609 KB
- Volume
- 54
- Category
- Article
- ISSN
- 0021-9614
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