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Complexes of the “proton sponge” 1,8-bis(dimethylamino)naphthalene (DMAN) Part VI. The structure of [DMANH]+ [pentafluorophenolate]− [pentafluorophenol]2

✍ Scribed by Natalia Odiaga; Jan A. Kanters; Bert T.G. Lutz; Eugenius Grech


Book ID
107806872
Publisher
Elsevier Science
Year
1992
Tongue
English
Weight
815 KB
Volume
273
Category
Article
ISSN
0022-2860

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Low-temperature (120 K) structure and vi
✍ Eugeniusz Grech; Zbigniew Malarski; Wanda Sawka-Dobrowolska; Lucjan Sobczyk 📂 Article 📅 1999 🏛 John Wiley and Sons 🌐 English ⚖ 111 KB 👁 1 views

Low-temperature (120 K) studies of the structure of the DMAN Á DCI adduct indicate that in symmetrical [NHN] hydrogen bridge of 2.571 (1) A ˚length (2.579(2) A ˚at room temperature) there is a disorder of the H-atom occupying two positions at nitrogen atoms with a distance of 0.94(3) A ˚. The compa